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sisvu:academicYear 2007 (xsd:int)
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sisvu:description Lecture type: lectures practice Exercise type: laboratory practice audio practice Knowledge verification: writing exam oral exam Purpose: To give the fundamental knowledge of modern organic chemistry and its application in industry. Subject content: Carbon compounds and chemical bonds. Structural theory: atomic and molecular orbitals, hybridization. Representative carbon compounds, intermolecular forces. An introduction to organic reactions: acids and bases. Alkanes and cycloalkanes: conformational analysis, ring strain, isomerism. Stereohemistry: isomers and stereoisomers, enantiomers and chiral molekules, diastereomers, (R)-(S) system, optical activity, separation of enantiomers, synthesis of chiral molekules (drugs). Ionic reactions: nucleophilic substitution (SN2 and SN1) and elimination (E2 and E1) reactions of alkyl halides. Alkenes and alkines: properties and synthesis, konfiguration of alkenes (E and Z), stereochemistry of addition reactions, carbocations and molecular rearrangements. Radical reactions: halogenation of alkanes, polymerization of alkenes. Alcohols and ethers: structure, properties, synthesis, reactions, crown ethers and phasetransfer catalysts, oxydations and reductions, organometallic compounds. (en)
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