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sisvu:academicYear 2008 (xsd:int)
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sisvu:description Chemical equilibrium. Acids and basis, buffers, (carbonate equilibrium, sea water as buffer, ion activity). Carbonate sediments (hydrolysis, carst phenomena, carbonate deposition, tuffa). Kinetics (chemical weathering, catalysis, complexation). Structural chemistry (bond types, isomorphism, polymorphism). Colloids, (organic, silica, Fe-Mn hydroxides, stability). Clay minerals and soil. Thermodynamic equilibria (phase rule, thermodynamic lows and functions). Eh-pH diagrams. Organic matter in sediments (diagenesis, epigenesis, maturation, genesis of oil and gas). Magma (Nernst coef. of distribution, REE, ionic potential, phase diagrams). Stabile isotopes, C,O,S,H, geothermometry. Radiogenic isotopes Rb/Sr, K/Ar, Ar/Ar, U-Th-Pb, Sm-Nd, 14C, geochronology. Historical geochemistry. (en)
sisvu:description Kemijska ravnoteža (homogena i heterogena. Kiseline i baze, puferi (karbonatna ravnoteža, morska voda kao pufer, pojam aktiviteta, realne vodene otopine). Karbonatni sedimenti (hidroliza, fenomeni krša, taloženje karbonata, tufa, sedre). Kinetika (kemijsko trošenje, kataliza i inhibicija, uloga humusnih kiselina, kompleksiranje. Strukturna kemija (tipovi veza, izomorfizam, polimorfizam). Koloidi (organski, silika, Fe-Mn hidroksidi, stabilnost). Minerali glina i tlo. Termodinamska ravnoteža (?pravilo faza?, osnovni termodinamski zakoni i funkcije). Eh-pH diagrami, (redox ravnoteža u vodenim otopinama). Organska tvar u sedimentima (dijageneza, epigeneza, maturacija, geneza nafte i plina). Kristalizacija magme, (Nernstov kvocijent razdjeljenja, elementi rijetkih zemalja, elementi u tragovima, ionski potencijal, fazni dijagrami). Stabilni izotopi C, O, S, H (geotermometrija). Radiogeni izotopi, Rb/Sr, K/Ar, Ar/Ar, U-Th-Pb, Sm/Nd, 14C (geokronologija). Historijska geokemija. (hr)
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